| S/No. | NAME | PERIOD OF TENURE |
| 1. | H.E. Dr. Tobias Mulimbika | 11.05.2023 to date |
| 2. | H.E. Mrs. Ndiyoi Muliwana Mutiti | 17.08.2015 to 05.01.2021 |
| 3. | H.E. Ng’ona Mwewa Chibesakunda | 14.01.2012 to 13.09.2015 |
| 4. | H.E. Dr. Mbukusita Wamundila Lewanika | 08.07.2009 to 12.2011 |
| 5. | H.E. Mr. Godfrey S. Simasiku | 12.09.2002 to 30.06.2009 |
| 6. | H.E. Mr. Elias Marko Chisha Chipimo | 27.07.2000 to 04.07.2001 |
| 7. | H.E. Prof. Lyson Potipher Tembo | 20.09.1996 to 16.05.2000 |
| 8. | H.E Mr. Joe Mwale | 28.05.1992 to 06.05.1995 |
| 9. | H.E. Mr. Boniface Salimu Zulu | 10.03.1987 to 15.01.1991 |
| 10. | H.E Axson Chalikulima | 1984-1987 |
| 11. | H.E Siyamunji | 1980-1983 |
| 12. | H.E Chief Mapanza | 1978-1980 |
| 13. | H.E Justice Lombe Chibesakunda | 1976-1978 |
